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Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3,   Pages 369-377 doi: 10.1007/s11705-014-1435-9

Abstract: Catalysts Pt/TiO and NiMo/Al O are highly active and selective for the hydrodeoxygenation of guaiacolNiMo/Al O and Pt/Al O are more active and selective for cyclohexane formation as compared with Pt/TiOHowever, Pt/TiO is stable while the other two catalysts deactivate due to the nature and amount of coke

Keywords: Pt/TiO<sub>2sub>     NiMo/Al<sub>2sub>O<sub>3sub>     Pt/Al<sub>2sub>O<sub>3sub>     bio-oil     hydrodeoxygenation    

Evaluation of H<sub>2sub> on the Evolution Mechanism of NO<sub>xsub> Storage and Reductionover Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> Catalysts Article

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Engineering 2019, Volume 5, Issue 3,   Pages 568-575 doi: 10.1016/j.eng.2019.02.005

Abstract:

In this investigation, Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> catalysts were preparedThe physical and chemical properties of the Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub>>xsub>, CeO<sub>2sub>, and BaCO<sub>3sub>, whose peaks were observed in X-ray diffraction(XRD) spectra, dispersed well on the γ-Al2O3, as shown by transmission electron microscope (TEM>catsub> at 350 °C, which was ascribed to the increase in NO<sub>2sub> yield.

Keywords: Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> catalysts     Physicochemical properties     NO<sub>xsub> storageand reduction     NO<sub>xsub> emission     H<sub>2sub> reductant    

The effect of preparation conditions of Pt/Al

Lei YUAN, Xiang ZHENG, Kaijiao DUAN, Hao HU, Jinggang WANG, Seong Ihl WOO, Zhiming LIU

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 457-463 doi: 10.1007/s11783-013-0512-5

Abstract: Selective catalytic reduction of NO by H in the presence of oxygen has been investigated over Pt/AlThe higher surface area and the presence of metallic Pt over Pt/Al O pre-treated by H or pretreated

Keywords: NO<sub>xsub> reduction     Pt/Al<sub>2sub>O<sub>3sub>     preparation condition     H<sub>2sub>-SCR    

Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 428-434 doi: 10.1007/s11783-013-0517-0

Abstract: nitrogen at temperatures range from 423K to 673K by selective catalytic oxidation (SCO) over a nanosized Pt-Rhoxygen content of 4%, approximately 99% of the NH was removed by catalytic oxidation over the nanosized Pt-RhTherefore, the application of nanosized Pt-Rh/γ-Al O catalyst can significantly enhance the catalyticindicates that EEFM spectroscopy was proven to be an appropriate and effective method to characterize the Ptclusters in intrinsic emission from nanosized Pt-Rh/γ-Al O catalyst.

Keywords: ammonia (NH<sub>3sub>)     nanosized Pt-Rh/γ-Al<sub>2sub>O<sub>3sub> catalyst     excitation-emission fluorescent    

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 6, doi: 10.1007/s11783-017-0976-9

Abstract: This present work investigated the effects of Pd doping on N O formation over Pt/BaO/Al O catalyst.Three types of catalysts, Pt/BaO/Al O , Pt/Pd mechanical mixing catalyst (Pt/BaO/Al O +Pd/Al O ) andPt-Pd co-impregnation catalyst (Pt-Pd/BaO/Al O ) were prepared by incipient wetness impregnation methodCompared with Pt/BaO/Al O , (Pt/BaO/Al O +Pd/Al O ) produced less N O and more NH during NO storageand reduction process, while an opposite trend was found over (Pt-Pd/BaO/Al O +Al O ).

Keywords: NO<sub>xsub> storage reduction     Pt/BaO/Al<sub>2sub>O<sub>3sub>     Pd doping     N<sub>2sub>O formation    

Decoration of CdMoO micron polyhedron with Pt nanoparticle and their enhanced photocatalytic performance

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1949-1961 doi: 10.1007/s11705-023-2360-6

Abstract: This study aimed to prepare and apply a novel Pt/CdMoO<sub>4sub> composite photocatalyst for photocatalyticN<sub>2sub> fixation and tetracycline degradation.The Pt/CdMoO<sub>4sub> composite was subjected to comprehensive investigation on the morphology, structureThe results demonstrate the dispersion of Pt nanoparticles on the CdMoO<sub>4sub> surface.work function value than CdMoO<sub>4sub>, resulting in electron drift from CdMoO<sub>4sub> to Pt

Keywords: photocatalytic N<sub>2sub> fixation     Pt/CdMoO<sub>4sub>     tetracycline degradation     Schottky barrier    

Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO

Yuxin YIN, Xin TAN, Feng HOU, Lin ZHAO

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 3,   Pages 298-304 doi: 10.1007/s11705-009-0019-6

Abstract: Furthermore, Pt nanoparticles were successfully deposited on the surface of TiO nanotubes by ac electrodepositionThe TiO /Pt composites were characterized by field emission scanning electron microscope (FESEM), X-rayAn enhancement in photocurrent density has been achieved upon modification of TiO nanotubes with Pt

Keywords: TiO<sub>2sub> nanotube arrays     HMT     TiO<sub>2sub>/Pt     Photocurrent density    

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords: Rh<sub>2sub>O<sub>3sub>     CePO<sub>4sub>     N<sub>2sub>O decomposition    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6,   Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr<sub>2</sub>O<sub>3</sub> system with AI<sub>2</sub>O<sub>3</sub>and Cr<sub>2</sub>O<sub>3</sub> diluents were conducted, and the effects of reactionstarting temperature T<sub>O</sub>, diluents AI<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub> on the adiabatic combustion temperature

Keywords: cermet     combustion synthesis     Al - Cr<sub>2sub>O<sub>3sub> system     thermodynamics     reaction model    

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords: Mn promotion     nickel catalysts     CO<sub>2sub> methanation     co-methanation of CO and CO<sub>2sub>    

Al<sub>2sub>O<sub>3sub> and CeO<sub>2sub>-promoted MgO sorbents for CO<sub>2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords: CO<sub>2sub> capture     MgO sorbents     Al<sub>2sub>O<sub>3sub>     CeO<sub>2sub>     flue gas    

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5,   Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunctionis constructed by in-situ integrating Bi<sub>2sub>S<sub>3sub> with the In<sub>2sub>S<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In<sub>2sub>S<sub>3sub> (0.32 mmol/(g∙h) and Bi<sub>2sub>S<sub>3sub> (0.41 mmol/(g∙h)), respectively.

Keywords: photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous interfacial contact    

Feasibility study of plasma sprayed Al<sub>2sub>O<sub>3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Frontiers of Mechanical Engineering 2012, Volume 7, Issue 4,   Pages 371-375 doi: 10.1007/s11465-012-0339-y

Abstract: Within this study the feasibility of plasma sprayed Al<sub>2sub>O<sub>3sub> coatings as diffusionAl<sub>2sub>O<sub>3sub> coatings were prepared by air plasma spraying (APS).The results showed that Al<sub>2sub>O<sub>3sub> could be well deposited onto CFC substrates.temperature of 1270°C, crack network formed within the coating, showing that the plasma sprayed Al<sub>2sub>O<sub>3sub> coatings are limited regarding to their application temperatures as diffusion

Keywords: diffusion barrier coatings     CFC     plasma spraying     microstructure     Al<sub>2sub>O<sub>3sub>    

Spray Preparation, Microstructure and Properties of Al<sub>2sub>O<sub>3sub>-M<sub>xsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Strategic Study of CAE 2002, Volume 4, Issue 9,   Pages 75-80

Abstract: carbon steel substrate, base coating of nickel-coated aluminium and intermediate coating of 50% Al<sub>2sub>O<sub>3sub> + 50% Ni were prepared by means of oxyacetylene spray, and final coating of Al<sub>2sub>O<sub>3sub> ~ M<sub>xsub>O<sub>ysub> was prepared by means of plasma spray.of 60% (mass) sulphuric acid with 60 % concentration, and 40% (mass) phosphoric ore powder, the Al<sub>2sub>O<sub>3sub> ~ M<sub>xsub>O<sub>ysub> coating resistance to corrosion and wear, is 7.46

Keywords: Al<sub>2sub>O<sub>3sub>-M<sub>xsub>O<sub>ysub>     coating     plasma     resistance to corrosion     resistance    

Title Author Date Type Operation

Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Journal Article

Evaluation of H<sub>2sub> on the Evolution Mechanism of NO<sub>xsub> Storage and Reductionover Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> Catalysts

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Journal Article

The effect of preparation conditions of Pt/Al

Lei YUAN, Xiang ZHENG, Kaijiao DUAN, Hao HU, Jinggang WANG, Seong Ihl WOO, Zhiming LIU

Journal Article

Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

Journal Article

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Journal Article

Decoration of CdMoO micron polyhedron with Pt nanoparticle and their enhanced photocatalytic performance

Journal Article

Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO

Yuxin YIN, Xin TAN, Feng HOU, Lin ZHAO

Journal Article

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

Al<sub>2sub>O<sub>3sub> and CeO<sub>2sub>-promoted MgO sorbents for CO<sub>2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Journal Article

Feasibility study of plasma sprayed Al<sub>2sub>O<sub>3sub> coatings as diffusion barrier on CFC

Kirsten BOBZIN, Lidong ZHAO, Nils KOPP, Thomas WARDA

Journal Article

Spray Preparation, Microstructure and Properties of Al<sub>2sub>O<sub>3sub>-M<sub>xsub>O Hard -

Wang Biao,Wang Yudong,Li Huiling,Zhang Zihua

Journal Article